Solvate-free bis(triphenylphosphine)iminium chloride
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چکیده
منابع مشابه
Solvate-free bis(triphenylphosphine)iminium chloride
The title compound, C(36)H(30)NP(2) (+)·Cl(-), crystallized in the solvate-free form from a CH(3)CN/OEt(2) solution. The chloride anion and the N atom of the [(Ph(3)P)(2)N](+) cation are located on a twofold axis, yielding overall symmetry 2 for the cation. The central P-N-P angle [133.0 (3)°] is at the low end of the range of observed P-N-P angles.
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The ions of the title chloro-form-solvated salt, C(11)H(17)N(2) (+)·Cl(-)·CHCl(3), are linked by a strong N-H⋯Cl hydrogen bond; the solvent mol-ecule also inter-acts with the chloride ion through a C-H⋯Cl hydrogen bond. Additionally, neighboring cations form weak hydrogen bonds to the anion, resulting in a supra-molecular ribbon that runs along the a axis.
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W o l f g a n g L i e b e l t , K u r t D e h n i c k e Fachbereich Chemie der Philipps-Universität Marburg, D-3550 Marburg/Lahn Z. Naturforsch. 84b, 942-948 (1979); eingegangen am 26. März 1979 Tungsten Nitride Chloride-P0Cl3 Solvate, Preparation, IR, Crystal Structure Tungsten nitride chloride-POCl3 solvate, [WNC13 • P0C13]4 • 2 POCl3 is prepared by the reaction of WNCI3 with excess POCI3. Wi...
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In the title complex, [InCl(2)(C(24)H(21)N(7))]Cl·C(2)H(5)OH·2H(2)O, the In(III) ion is coordinated by four N atoms from the tris-(benz-imidazol-2-ylmeth-yl)amine (NTB) ligand and two Cl atoms in a distorted octa-hedral environment. In the crystal structure, inter-molecular N-H⋯O, O-H⋯O, O-H⋯Cl and weak C-H⋯Cl hydrogen bonds connect the cations, anions and solvent mol-ecules into a three-dimens...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810046325